Structural Characterization of Lignin Isolated from Wheat-Straw during the Alkali Cooking Process

Phenolation of alkali lignin of wheat straw in ionic liquid

Effect of hydrothermal pretreatment on the structural changes of alkaline ethanol lignin from wheat straw

Due to the enormous abundance of lignin and its unique aromatic nature, lignin has great potential for the production of industrially useful fuels, chemicals, and materials. However, the rigid and compact structure of the plant cell walls significantly blocks the separation of lignin. In this study, wheat straw was hydrothermally pretreated at different temperatures (120-200 °C) followed by pos...

Thermogravimetric Characteristics of Wheat Straw Lignin

The thermogravimetric characteristics of wheat straw EMAL (Enzymatic Acidolysis Lignin) were analyzed. The effect of the heating rates on the thermogravimetric characteristics of wheat straw and the wheat straw influence on pyrolysis were investigated. The influence of various heating rates on wheat straw was significant, the pyrolysis rate of wheat straw EMAL increased at temperatures between ...

Demethylation of Wheat Straw Alkali Lignin for Application in Phenol Formaldehyde Adhesives

Lignin is a natural biopolymer with a complex three-dimensional network. It is the second most abundant natural polymer on earth. Commercially, lignin is largely obtained from the waste liquors of pulping and bioethanol productions. In this study, wheat straw alkali lignin (WSAL) was demethylated by using an in-situ generated Lewis acid under an optimized demethylation process. The demethylatio...

Structural characterization of wheat straw lignin as revealed by analytical pyrolysis, 2D-NMR, and reductive cleavage methods.

The structure of the lignin in wheat straw has been investigated by a combination of analytical pyrolysis, 2D-NMR, and derivatization followed by reductive cleavage (DFRC). It is a p-hydroxyphenyl-guaiacyl-syringyl lignin (with an H:G:S ratio of 6:64:30) associated with p-coumarates and ferulates. 2D-NMR indicated that the main substructures present are β-O-4'-ethers (∼~75%), followed by phenyl...